6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione

In the title compound, C23H28N2O 5, the 4,5-dihydro-isoxazole ring adopts a slight envelope conformation and the dioxolane ring is in a twisted conformation. The mol-ecular structure, in the vicinity of the benzyl group, may be influenced by an intra-molecular C- H⋯O hydrogen bond which generates an...

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Published in:Acta Crystallographica Section E: Structure Reports Online
Main Author: Bathich Y.; Shaameri Z.; Hamzah A.S.; Quah C.K.; Fun H.-K.
Format: Article
Language:English
Published: 2009
Online Access:https://www.scopus.com/inward/record.uri?eid=2-s2.0-70449379659&doi=10.1107%2fS1600536809044675&partnerID=40&md5=ffcace3f89327e3e544389cbe1397079
id 2-s2.0-70449379659
spelling 2-s2.0-70449379659
Bathich Y.; Shaameri Z.; Hamzah A.S.; Quah C.K.; Fun H.-K.
6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione
2009
Acta Crystallographica Section E: Structure Reports Online
65
11
10.1107/S1600536809044675
https://www.scopus.com/inward/record.uri?eid=2-s2.0-70449379659&doi=10.1107%2fS1600536809044675&partnerID=40&md5=ffcace3f89327e3e544389cbe1397079
In the title compound, C23H28N2O 5, the 4,5-dihydro-isoxazole ring adopts a slight envelope conformation and the dioxolane ring is in a twisted conformation. The mol-ecular structure, in the vicinity of the benzyl group, may be influenced by an intra-molecular C- H⋯O hydrogen bond which generates an S(7) ring motif. In the crystal structure, mol-ecules are linked via weak inter-molecular C- H⋯O hydrogen bonds, forming extended chains along the b axis. Further stabilization is provided by weak C- H⋯π inter-actions.

16005368
English
Article
All Open Access; Gold Open Access; Green Open Access
author Bathich Y.; Shaameri Z.; Hamzah A.S.; Quah C.K.; Fun H.-K.
spellingShingle Bathich Y.; Shaameri Z.; Hamzah A.S.; Quah C.K.; Fun H.-K.
6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione
author_facet Bathich Y.; Shaameri Z.; Hamzah A.S.; Quah C.K.; Fun H.-K.
author_sort Bathich Y.; Shaameri Z.; Hamzah A.S.; Quah C.K.; Fun H.-K.
title 6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione
title_short 6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione
title_full 6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione
title_fullStr 6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione
title_full_unstemmed 6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione
title_sort 6-Benzyl-3-(1,4-dioxaspiro-[4.5]decan-2-yl)-8,8-dimethyl-1-oxa-2, 6-diaza-spiro-[4.4]non-2-ene-7,9-dione
publishDate 2009
container_title Acta Crystallographica Section E: Structure Reports Online
container_volume 65
container_issue 11
doi_str_mv 10.1107/S1600536809044675
url https://www.scopus.com/inward/record.uri?eid=2-s2.0-70449379659&doi=10.1107%2fS1600536809044675&partnerID=40&md5=ffcace3f89327e3e544389cbe1397079
description In the title compound, C23H28N2O 5, the 4,5-dihydro-isoxazole ring adopts a slight envelope conformation and the dioxolane ring is in a twisted conformation. The mol-ecular structure, in the vicinity of the benzyl group, may be influenced by an intra-molecular C- H⋯O hydrogen bond which generates an S(7) ring motif. In the crystal structure, mol-ecules are linked via weak inter-molecular C- H⋯O hydrogen bonds, forming extended chains along the b axis. Further stabilization is provided by weak C- H⋯π inter-actions.
publisher
issn 16005368
language English
format Article
accesstype All Open Access; Gold Open Access; Green Open Access
record_format scopus
collection Scopus
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