Influence of Pr substitution on acoustic gruneisen parameter and lattice vibrational anharmonicity contribution in ceramic superconductors

• Published in: Journal of Physics: Conference Series
• Main Author: Yahya A.K.
• Format: Article
• Language: English
• Published: Institute of Physics Publishing 2009
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-65749110207&doi=10.1088%2f1742-6596%2f153%2f1%2f012037&partnerID=40&md5=0b0c709bdaf9ad50103cacf146e8e780

This paper reports the effect of Pr substitution on lattice anharmonicity contribution to temperature dependent longitudinal and shear ultrasonic velocity data in (Er1-xPrx)Ba2Cu3O 6.9 (x 0.0, 0.1 and 0.2) and TlSr2(Ca1-yPr y)Cu2O7 (y 0.5 and 1.0) superconductors. Pr was observed to influence the deviation of the elastic behaviour of both samples from the lattice anharmonicity curves at higher temperatures. The calculated effective Gruneisen parameter for the longitudinal mode (γeffL) for both compounds was found to increase with Pr content, indicating increasing anharmonicity contribution. In addition, both series also showed that γeffL is larger than the effective Gruneisen parameter for the shear mode (γeffL) throughout the substitution. The influence of Pr substitution on γeff and the BCS electron-phonon coupling constant (λ) as well as its possible relationship to superconductivity are discussed. © 2009 IOP Publishing Ltd.