Fixed-bed adsorption of metal ions from aqueous solution on polyethyleneimine-impregnated palm shell activated carbon

• Published in: Chemical Engineering Journal
• Main Author: Yin C.Y.; Aroua M.K.; Daud W.M.A.W.
• Format: Article
• Language: English
• Published: 2009
• Online Access: https://www.scopus.com/inward/record.uri?eid=2-s2.0-60949093758&doi=10.1016%2fj.cej.2008.07.032&partnerID=40&md5=0974f6b160a31b5fcf705479f6899cb4

Fixed-bed adsorption studies with virgin and polyethyleneimine (PEI)-impregnated palm shell activated carbon (AC) as a media for the removal of single Ni2+ or Cu2+ ions from aqueous solution were conducted. The studies were conducted in a vertical down flow Perspex column with influent pH at 5 with either Ni2+ or Cu2+ had an influent concentration of 1 mmol/L. The adsorption data were fitted to three-well-established fixed-bed adsorption models, namely, bed-depth-service-time (BDST), Thomas and Yoon-Nelson models. It was observed that PEI impregnation at 8.41 wt% had increased the breakthrough volume and service time of AC by factors of 2.1 (Cu2+) and 1.6 (Ni2+) as compared to virgin AC. For Cu2+ adsorption, the modelled BDST, Thomas and Yoon-Nelson curves were in very good agreement with the experimental curves while it was conversely true for Ni2+ adsorption. © 2008 Elsevier B.V. All rights reserved.